Dioxygen activation and two consecutive oxidative decarboxylations of phenylpyruvate by nonheme iron(II) complexes: functional models of hydroxymandelate synthase (HMS) and CloR.
نویسندگان
چکیده
Two mononuclear iron(ii)-phenylpyruvate complexes of monoanionic facial N3 ligands are reported to react with dioxygen to undergo two consecutive oxidative decarboxylation steps via an iron-mandelate complex mimicking the function of HMS and CloR.
منابع مشابه
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عنوان ژورنال:
- Chemical communications
دوره 51 36 شماره
صفحات -
تاریخ انتشار 2015